Water permeability of nanoporous graphene at realistic pressures for reverse osmosis desalination David Cohen-Tanugi and Jeffrey C. Grossman Citation: The Journal of Chemical Physics 141, 074704 (2014); doi: 10.1063/1.4892638 View online: http://dx.doi.org/10.1063/1.4892638 View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/141/7?ver=pdfcov Published by the AIP Publishing Articles you may be interested in Mechanical properties of nanoporous graphene membrane J. Appl. Phys. 115, 034303 (2014); 10.1063/1.4862312 Water permeation through single-layer graphyne membrane J. Chem. Phys. 139, 064705 (2013); 10.1063/1.4817596 Zeolitic imidazolate framework-8 as a reverse osmosis membrane for water desalination: Insight from molecular simulation J. Chem. Phys. 134, 134705 (2011); 10.1063/1.3573902 Reverse osmosis desalination: Modeling and experiment Appl. Phys. Lett. 94, 124102 (2009); 10.1063/1.3109795 Partitioning of salt ions in FT30 reverse osmosis membranes Appl. Phys. Lett. 91, 181904 (2007); 10.1063/1.2802562

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THE JOURNAL OF CHEMICAL PHYSICS 141, 074704 (2014)

Water permeability of nanoporous graphene at realistic pressures for reverse osmosis desalination David Cohen-Tanugi and Jeffrey C. Grossman Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA

(Received 2 June 2014; accepted 29 July 2014; published online 18 August 2014) Nanoporous graphene (NPG) shows tremendous promise as an ultra-permeable membrane for water desalination thanks to its atomic thickness and precise sieving properties. However, a significant gap exists in the literature between the ideal conditions assumed for NPG desalination and the physical environment inherent to reverse osmosis (RO) systems. In particular, the water permeability of NPG has been calculated previously based on very high pressures (1000–2000 bars). Does NPG maintain its ultrahigh water permeability under real-world RO pressures (

Water permeability of nanoporous graphene at realistic pressures for reverse osmosis desalination.

Nanoporous graphene (NPG) shows tremendous promise as an ultra-permeable membrane for water desalination thanks to its atomic thickness and precise si...
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