Frontispiece: asymmetric reduction of α-amino ketones with a KBH4 solution catalyzed by Chiral Lewis acids.

Direct asymmetric amination of α-branched cyclic ketones catalyzed by a chiral phosphoric acid.

Chiral Pyridoxal-Catalyzed Asymmetric Biomimetic Transamination of α-Keto Acids.

Iron catalyzed asymmetric hydrogenation of ketones.

Cobalt-catalyzed asymmetric hydroboration of aryl ketones with pinacolborane.

Copper-catalyzed asymmetric hydroboration of α-dehydroamino acid derivatives: facile synthesis of chiral β-hydroxy-α-amino acids.

Asymmetric epoxidation of unsaturated ketones catalyzed by heterobimetallic rare earth-lithium complexes bearing phenoxy-functionalized chiral diphenylprolinolate ligand.

Asymmetric synthesis ofα-substitutedβ-amino acids using aβ-alanine derivative with two chiral handles.

A chiral borane catalyzed asymmetric hydrosilylation of imines.

Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.

nBu4NI-catalyzed oxidative imidation of ketones with imides: synthesis of α-amino ketones.

A highly enantioselective hydrogenation of silyl enol ethers catalyzed by chiral frustrated Lewis pairs.

Chiral Lewis acid catalyzed asymmetric cycloadditions of disubstituted ketenes for the synthesis of β-lactones and δ-lactones.

Chiral silicon Lewis acids having a pentacoordinate stereogenic silicon center: 29Si NMR studies and application to asymmetric Diels-Alder reactions.

Expedient synthesis of chiral α-amino acids through nickel-catalyzed reductive cross-coupling.

Nickel-catalyzed asymmetric ring opening of oxabenzonorbornadienes with arylboronic acids.

Synthesis of chiral N-phosphinyl α-imino esters and their application in asymmetric synthesis of α-amino esters by reduction.

Asymmetric Synthesis of Axially Chiral Isoquinolones: Nickel-Catalyzed Denitrogenative Transannulation.

enantioselective-reduction sequence.

Catalytic Asymmetric Mannich Reactions with Fluorinated Aromatic Ketones: Efficient Access to Chiral β-Fluoroamines.

Asymmetric α-amination reaction of alkenyl trifluoroacetates catalyzed by a chiral phosphine-silver complex.

Enantio- and diastereoselective asymmetric allylic alkylation catalyzed by a planar-chiral cyclopentadienyl ruthenium complex.

Asymmetric synthesis of α-chiral hydroxyalkylphosphines by a catalytic enantioselective reduction of acylphosphines.

Fluorous chiral bisoxazolines: application in copper-catalyzed asymmetric α-hydrophosphonylation.

Asymmetric hydroamination catalyzed by a new chiral zirconium system: reaction scope and mechanism.

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Direct asymmetric amination of α-branched cyclic ketones catalyzed by a chiral phosphoric acid.

Chiral Pyridoxal-Catalyzed Asymmetric Biomimetic Transamination of α-Keto Acids.

Iron catalyzed asymmetric hydrogenation of ketones.

Cobalt-catalyzed asymmetric hydroboration of aryl ketones with pinacolborane.

Copper-catalyzed asymmetric hydroboration of α-dehydroamino acid derivatives: facile synthesis of chiral β-hydroxy-α-amino acids.

Asymmetric epoxidation of unsaturated ketones catalyzed by heterobimetallic rare earth-lithium complexes bearing phenoxy-functionalized chiral diphenylprolinolate ligand.

Asymmetric synthesis ofα-substitutedβ-amino acids using aβ-alanine derivative with two chiral handles.

A chiral borane catalyzed asymmetric hydrosilylation of imines.

Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.

nBu4NI-catalyzed oxidative imidation of ketones with imides: synthesis of α-amino ketones.

A highly enantioselective hydrogenation of silyl enol ethers catalyzed by chiral frustrated Lewis pairs.

Chiral Lewis acid catalyzed asymmetric cycloadditions of disubstituted ketenes for the synthesis of β-lactones and δ-lactones.

Chiral silicon Lewis acids having a pentacoordinate stereogenic silicon center: 29Si NMR studies and application to asymmetric Diels-Alder reactions.

Expedient synthesis of chiral α-amino acids through nickel-catalyzed reductive cross-coupling.

Nickel-catalyzed asymmetric ring opening of oxabenzonorbornadienes with arylboronic acids.

Synthesis of chiral N-phosphinyl α-imino esters and their application in asymmetric synthesis of α-amino esters by reduction.

Asymmetric Synthesis of Axially Chiral Isoquinolones: Nickel-Catalyzed Denitrogenative Transannulation.

enantioselective-reduction sequence.

Catalytic Asymmetric Mannich Reactions with Fluorinated Aromatic Ketones: Efficient Access to Chiral β-Fluoroamines.

Asymmetric α-amination reaction of alkenyl trifluoroacetates catalyzed by a chiral phosphine-silver complex.

Enantio- and diastereoselective asymmetric allylic alkylation catalyzed by a planar-chiral cyclopentadienyl ruthenium complex.

Asymmetric synthesis of α-chiral hydroxyalkylphosphines by a catalytic enantioselective reduction of acylphosphines.

Fluorous chiral bisoxazolines: application in copper-catalyzed asymmetric α-hydrophosphonylation.

Asymmetric hydroamination catalyzed by a new chiral zirconium system: reaction scope and mechanism.

Frontispiece: asymmetric reduction of α-amino ketones with a KBH4 solution catalyzed by Chiral Lewis acids.

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