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Corrigendum: On the Thermal and Thermodynamic (In)Stability of Methylammonium Lead Halide Perovskites Bruno Brunetti, Carmen Cavallo, Andrea Ciccioli, Guido Gigli & Alessandro Latini Scientific Reports 6:31896; doi: 10.1038/srep31896; published online 22 August 2016; updated on 27 July 2017 This Article contains errors. In the ‘Thermal Stability: Non-Ambient X-ray Diffraction’ section, under subheading ‘Thermodynamic stability: Knudsen effusion mass spectrometry and Knudsen effusion mass loss’, “The resulting values of ∆ f H(298 ° K ) were: −688.3 ± 7.8 kJ/mol, −567.5 ± 8.7 kJ/mol, and −403.6 ± 9.7 kJ/mol for MAPbCl3, MAPbBr3 and MAPbI3, respectively”. should read: “The resulting values of ∆ f H(298 ° K ) were: −660.5 ± 7.8 kJ/mol, −539.6 ± 8.7 kJ/mol, and −375.7 ± 9.7 kJ/mol for MAPbCl3, MAPbBr3 and MAPbI3, respectively”. In Equation (13), “∆r GT (CH3 NH3 PbCl3 (s) ) = [(194.8 ± 6.0) − (275.5 ± 6.8)10−3 T /K ] kJ/mol” should read: “∆r GT (CH3 NH3 PbCl3 (s) ) = [(185.6 ± 6.0) − (250.4 ± 6.8)10−3 T /K ] kJ/mol” In Equation (14), “∆r GT (CH3 NH3 PbBr3 (s) ) = [(212.2 ± 7.1) − (273.4 ± 10.2)10−3 T /K ] kJ/mol” should read: “∆r GT (CH3 NH3 PbBr3 (s) ) = [(203.4 ± 7.1) − (251.3 ± 10.2)10−3 T /K ] kJ/mol” In Equation (15), “∆r GT (CH3 NH3 PbI3 (s) ) = [(215.4 ± 8.3) − (280.2 ± 10.6)10−3 T /K ] kJ/mol” should read: “∆r GT (CH3 NH3 PbI3 (s) ) = [(201.4 ± 8.3) − (243.1 ± 10.6)10−3 T /K ] kJ/mol”
Scientific Reports | 7:46867 | DOI: 10.1038/srep46867
1
www.nature.com/scientificreports/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ © The Author(s) 2017
Scientific Reports | 7:46867 | DOI: 10.1038/srep46867
2
OPEN
Corrigendum: On the Thermal and Thermodynamic (In)Stability of Methylammonium Lead Halide Perovskites Bruno Brunetti, Carmen Cavallo, Andrea Ciccioli, Guido Gigli & Alessandro Latini Scientific Reports 6:31896; doi: 10.1038/srep31896; published online 22 August 2016; updated on 27 July 2017 This Article contains errors. In the ‘Thermal Stability: Non-Ambient X-ray Diffraction’ section, under subheading ‘Thermodynamic stability: Knudsen effusion mass spectrometry and Knudsen effusion mass loss’, “The resulting values of ∆ f H(298 ° K ) were: −688.3 ± 7.8 kJ/mol, −567.5 ± 8.7 kJ/mol, and −403.6 ± 9.7 kJ/mol for MAPbCl3, MAPbBr3 and MAPbI3, respectively”. should read: “The resulting values of ∆ f H(298 ° K ) were: −660.5 ± 7.8 kJ/mol, −539.6 ± 8.7 kJ/mol, and −375.7 ± 9.7 kJ/mol for MAPbCl3, MAPbBr3 and MAPbI3, respectively”. In Equation (13), “∆r GT (CH3 NH3 PbCl3 (s) ) = [(194.8 ± 6.0) − (275.5 ± 6.8)10−3 T /K ] kJ/mol” should read: “∆r GT (CH3 NH3 PbCl3 (s) ) = [(185.6 ± 6.0) − (250.4 ± 6.8)10−3 T /K ] kJ/mol” In Equation (14), “∆r GT (CH3 NH3 PbBr3 (s) ) = [(212.2 ± 7.1) − (273.4 ± 10.2)10−3 T /K ] kJ/mol” should read: “∆r GT (CH3 NH3 PbBr3 (s) ) = [(203.4 ± 7.1) − (251.3 ± 10.2)10−3 T /K ] kJ/mol” In Equation (15), “∆r GT (CH3 NH3 PbI3 (s) ) = [(215.4 ± 8.3) − (280.2 ± 10.6)10−3 T /K ] kJ/mol” should read: “∆r GT (CH3 NH3 PbI3 (s) ) = [(201.4 ± 8.3) − (243.1 ± 10.6)10−3 T /K ] kJ/mol”
Scientific Reports | 7:46867 | DOI: 10.1038/srep46867
1
www.nature.com/scientificreports/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ © The Author(s) 2017
Scientific Reports | 7:46867 | DOI: 10.1038/srep46867
2
